湿法脱硫净烟气相变凝聚促进SO3酸雾脱除技术研究综述A Research Review of SO3 Acid Mist Removal from Net Flue Gas Promoted by Phase Change Condensation Technology of Wet Desulfurization
王润生,孔伟,杨志国,程常杰,曲欣,詹凌霄,杨林军
WANG Runsheng,KONG Wei,YANG Zhiguo,CHENG Changjie,QU Xin,ZHAN Lingxiao,YANG Linjun
摘要(Abstract):
燃煤烟气中的SO_3排入大气环境会对生态环境和人体健康造成严重危害,有效控制其排放是当前关注的热点问题。为此,分析了燃煤烟气SO_3排放控制技术的研究进展及其不足,探讨了促进SO_3酸雾长大的团聚凝聚技术方法,结合国内外研究及国内相关领域政策环境,介绍了相变凝聚工作原理及其促进脱硫净烟气中SO_3酸雾脱除技术的研究现状及进展。最后,提出了基于相变凝聚技术进行SO_3排放控制研究的方向和重点。
The emitted SO_3 from coal-fired flue gas into the atmosphere imperils the ecological environment and human health. The SO_3 emission control now is a central issue that draws common attention. Therefore,the paper analyzes research progress and shortcomings of SO_3 emission control technology from coal-fired flue gas and discusses the agglomeration and coagulation technologies to promote the growth of SO_3 acid mist. Then,based on the domestic and foreign research and relevant domestic policy environment,the paper introduces the working principle of phase change condensation and the research status and progress of promoting the removal of SO_3 acid mist after desulfurization. Finally,it proposes the direction and focus of SO_3 emission control research based on phase change condensation technology.
关键词(KeyWords):
燃煤电厂;SO_3;相变凝聚;脱除;湿法烟气脱硫
coal-fired power plant;SO_3;phase change condensation;removal;wet flue gas desulfurization
基金项目(Foundation): 八师石河子市重大科技项目(2018ZD01);; 八师石河子市重点实验室项目(2019PT01);; 八师石河子市重点领域创新团队计划项目(2019TD02)
作者(Author):
王润生,孔伟,杨志国,程常杰,曲欣,詹凌霄,杨林军
WANG Runsheng,KONG Wei,YANG Zhiguo,CHENG Changjie,QU Xin,ZHAN Lingxiao,YANG Linjun
DOI: 10.19585/j.zjdl.202206013
参考文献(References):
- [1]莫华,朱杰.燃煤电厂有色烟羽治理要点分析与环境管理[J].中国电力,2019,52(3):10-15.
- [2]杨彦.火力发电厂湿法烟气脱硫系统烟囱腐蚀与防腐研究[D].北京:北京交通大学,2010.
- [3]ZHENG C,WANG Y,YANG Z,et al.Formation,transformation,measurement,and control of SO3in coal-fired power plants[J].Fuel,2019(1):327-346.
- [4]VAINIO E,FLEIG D,BRINK A,et al.Experimental evaluation and field application of a salt method for SO3measurement in flue gases[J].Energy&Fuels,2013,27(5):2767-2775.
- [5]胡斌,刘勇,任飞,等.低低温电除尘协同脱除细颗粒与SO3实验研究[J].中国电机工程学报,2016,36(16):4319-4325.
- [6]SRIVASTAVA R K,MILLER C A,ERICKSON C,et al.Emissions of sulfur trioxide from coal-fired power plants[J].Journal of the Air&Waste Management Association,2004,54(6):750-762.
- [7]潘丹萍,吴昊,杨林军,等.电厂湿法脱硫系统对烟气中细颗粒物及SO3酸雾脱除作用研究[J].中国电机工程学报,2016,36(16):4356-4362.
- [8]QI L,YUAN Y.Influence of SO3 in flue gas on electrostatic precipitability of high-alumina coal fly ash from a power plant in China[J].Powder Technology,2013,245:163-167.
- [9]YANG Z,ZHENG C,GAO X,et al.Sulfuric acid aerosol formation and collection by corona discharge in a wet electrostatic precipitator[J].Energy&Fuels,2017,31(8):8400-8406.
- [10]PAN D,YANG L,WU H,et al.Removal characteristics of sulfuric acid aerosols from coal-fired power plants[J].Journal of the Air&Waste Management Association,2017,67(3):352-357.
- [11]ZHENG C,HONG Y,XU Z,et al.Experimental study on removal characteristics of SO3by wet flue gas desulfurization absorber[J].Energy&Fuels,2018,32(5):6031-6038.
- [12]CAO Y,ZHOU H,JIANG W,et al.Studies of the fate of sulfur trioxide in coal-fired utility boilers based on modified selected condensation methods[J].Environmental Science&Technology,2010,44(9):3429-3434.
- [13]HOFFMANN T L.Environmental implications of acoustic aerosol agglomeration[J].Ultrasonics,2000,38(1-8):353-357.
- [14]胡斌,刘勇,杨春敏,等.化学团聚促进电除尘脱除烟气中PM2.5和SO3[J].化工学报,2016,67(9):3902-3909.
- [15]NINOMIYA Y,WANG Q,XU S,et al.Effect of additives on the reduction of PM2.5emissions during pulverized coal combustion[J].Energy&Fuels,2009,23(7):92-93.
- [16]FELDMAN P,BALASIC P.Development of the fine particle agglomerator[R].[S.l.]:EEC Information,1999.
- [17]YANG L,BAO J,YAN J,et al.Removal of fine particles in wet flue gas desulfurization system by heterogeneous condensation[J].Journal of Southeast University,2009,156(1):25-32.
- [18]BAO J,YANG L,YAN J,et al.Experimental study of fine particles removal in the desulfurized scrubbed flue gas[J].Fuel,2013(11):73-79.
- [19]WU H,PAN D,JIANG Y,et al.Improving the removal of fine particles from desulfurized flue gas by adding humid air[J].Fuel,2016(15):153-161.
- [20]ZHANG R,WU H,X SI,et al.Improving the removal of fine particulate matter by heterogeneous condensation in desulfurized flue gas[J].Fuel Processing Technology,2018,174:9-16.
- [21]GRIGONYTE J,NUUTINEN I,KOPONEN T,et al.Evaluation of a heat exchanger designed for efficient fine particle precipitation in small-scale wood combustion[J].Energy&Fuels,2014,28(9):6058-6065.
- [22]GROHN A,SUONMAA V,AUVINEN A,et al.Reduction of fine particle emissions from wood combustion with optimized condensing heat exchangers[J].Environmental Science&Technology,2009,43(16):6269-6274.
- [23]潘丹萍,吴昊,姜业正,等.应用水汽相变促进湿法脱硫净烟气中PM2.5和SO3酸雾脱除的研究[J].燃料化学学报,2016,44(1):113-119.
- [24]WU H,PAN D,HONG G,et al.Removal of sulfuric acid aerosols in desulfurized flue gas by adding moist air[J].Journal of Chemical Technology&Biotechnology,2017,92:1026-1034.
- [25]吴昊.应用水汽相变促进燃煤烟气中细颗粒物及SO3酸雾脱除的研究[D].南京:东南大学,2017.
- [26]雒飞,胡斌,吴昊,等.湿式电除尘对PM2.5/SO3酸雾脱除特性的试验研究[J].东南大学学报(自然科学版),2017,47(1):91-97.
- [27]YANG Z,ZHENG C,GAO X,et al.Highly efficient removal of sulfuric acid aerosol by a combined wet electrostatic precipitator[J].RSC Advances,2018(8):59-66.
- [28]梁成思.燃煤烟气中气溶胶颗粒形成及长大的机理研究[D].杭州:浙江大学,2019.
- [29]王述浩,李水清,段璐,等.相变凝聚器内蒸汽凝结与细颗粒团聚规律研究[J].中国电机工程学报,2017,37(24):7230-7236.
- [30]CAO R,TAN H,XIONG Y,et al.Improving the removal of particles and trace elements from coal-fired power plants by combining a wet phase transition agglomerator with wet electrostatic precipitator[J].Journal of Cleaner Production,2017,161:1459-1465.
- 燃煤电厂
- SO_3
- 相变凝聚
- 脱除
- 湿法烟气脱硫
coal-fired power plant - SO_3
- phase change condensation
- removal
- wet flue gas desulfurization