吴芳芳,汤治,章月芳
WU Fang-fang1,TANG Zhi1,ZHANG Yue-fang2(1.Zhejiang Electric Power Test and Research Institute

• 1:浙江省电力试验研究院
• 2:杭州意能电力技术有限公司

摘要(Abstract)：

应用电感耦合等离子体发射光谱法(ICP-AES),可同时测定火力发电厂锅炉水冷壁管垢清洗液中的钾、钙、钠、镁、铝、铜、铁、锰、磷、硅等元素,对ICP工作参数选择、元素分析线选择、酸度对测定的影响以及铁的干扰等进行了研究。试验证明,各元素的加标回收率在95%～106%之间,该方法具有灵敏度高、分析速度快、多元素同时测定、操作简便等优点。
The method of inductively coupled plasma-atomic emission spectrometry(ICP-AES) is applied to simultaneously determine K,Ca,Na,Mg,Al,Cu,Fe,Mn,P and Si in cleaning fluid of water-wall tube scale for boilers in thermal power plants.The ICP working parameter selection,element analysis line selection,acid influence on determination and iron interference are studied.The test results show that the standard addition recovery rate of each element is 95%~106% and it is featured by high sensitivity,high speed of analysis,simultaneous determination of multiple elements and convenient operation.

关键词(KeyWords)： 等离子体;发射光谱;水冷壁;管垢;多元素;干扰
plasma;emission spectrometry;water wall;tube scale;multiple elements;interference

Abstract:

Keywords:

基金项目(Foundation):

作者(Author): 吴芳芳,汤治,章月芳
WU Fang-fang1,TANG Zhi1,ZHANG Yue-fang2(1.Zhejiang Electric Power Test and Research Institute

DOI: 10.19585/j.zjdl.2012.05.009

参考文献(References)：

• 郝新焕,王帝,何丽丽.离子色谱测定垢样中的重金属离子[J].工业水处理,2008,28(9):77-79.
• 周少玲,鞠丽霞.汽轮机垢样常规分析方法的改进[J].热力发电,2009,36(9):78-94.
• 辛仁轩.等离子体发射光谱分析[M].北京:化学工业出版社,2004.
• 费浩,王树安,张泓澎.电感耦合等离子体原子发射光谱法测定不锈钢中元素[J].分析试验室,2009,28(5):268-271.
• 吕杰.ICP-AES法同时测定饮用水中的Pb,As等11种金属元素[J].光谱学与光谱分析,2003,23(4):779-784.